内容简介:
本书系统介绍了纳米尺度下光子学和光谱学的基本物理原理,以及它们的相互作用机制。还介绍了金属表面等离激元的激发、探测、和对分子光谱的增强机制,其中包括表面等离基元增强的吸收、荧光、拉曼、光学成像等。此外,还揭示了表面等离基元和激子耦合相互作用的物理机制,进一步阐释了这种相互作用在表面催化反应中的应用。
本书结构完整,物理原理阐述清晰,列举的应用例子是最新的科学前沿研究。
本书适合作为研究生和高年级本科生的光学教材,以及作为相关领域科研工作者的基础参考书。
作者简介:
孙萌涛教授,主要从事基于表面等离激元增强的分子拉曼光谱的实验和理论研究。研发高真空针尖增强拉曼光谱仪,实现目标分子拉曼光谱的超灵敏检测,并揭示表面等离激元增强拉曼光谱的物理和化学机制。以通讯作者(或第一作者)在国际重要学术期刊上发表SCI 论文超过200 篇(其中ESI高引论文12篇)。所有论文引用超过7000次,H-index 45。Researcher ID: B-1131-2008。10次应邀在国际重要期刊撰写本领域的综述。应邀撰写英文专著5 部(第一作者)。2016 年,获辽宁省科学技术(自然科学)二等奖(个人第二)。
目 录:
CHAPTER 1 Introduction
1.1Concept of Spectroscopy
1.2Concept of Photonics and Plasmonics
1.3Concept of PlasmonEnhanced Spectroscopy
1.3.1Plasmonenhanced fluorescence
1.3.2Plasmonenhanced resonance fluorescence energy
transfer
1.3.3Surfaceenhanced Raman scattering
1.3.4The remoteexcitation of SERS
1.3.5Tipenhanced Raman scattering spectroscopy
1.3.6Remote excitationTERS microscopy
1.3.7Plasmonenhanced coherence antiStokes Raman scattering images
References
CHAPTER 2 Molecular Spectroscopy
2.1Jablonski Diagram
2.2Electronic State Transition
2.2.1Ultravioletvisiblenear IR absorption
spectroscopy
2.2.2Twophoton absorption spectroscopy
2.2.3Fluorescence spectroscopy
2.2.4Fluorescence resonance energy transfer
2.3Vibration Spectroscopy
2.3.1Raman spectroscopy
2.3.2Infrared spectroscopy
2.3.3Modes of molecular vibration
2.3.4The difference between Raman and spectra
2.4Rotational State
2.5Electronic and Vibrational Spectroscopy by Circularly
Polarized Light
2.5.1Electronic circular dichroism
2.5.2Raman optical activity
References
CHAPTER 3 Photonics and Plasmonics
3.1Introduction
3.2Exciton
3.2.1Brief introduction of exciton
3.2.2Exciton classification
3.3Polariton
3.3.1Brief introduction of polariton
3.3.2Polariton types
3.4Plasmon and Surface Plasmons
3.4.1Plasmons
3.4.2Surface plasmons
3.4.3Surface plasmon polaritons
3.5PlasmonExciton Coupling: Plexciton
References
CHAPTER 4 Surface Plasmon
4.1Brief Introduction of Surface Plasmon
4.2Physical Mechanism of Surface Plasmon
4.2.1Drude model
4.2.2Relationship between refractive index and dielectric constant
4.2.3Dispersion relation
4.3Localized Surface Plasmon
4.4Plasmonic Waveguide
4.4.1The electromagnetic theory for calculating NWs
4.4.2The decay rate in the plasmon mode
4.4.3The spontaneous emission near the natip
4.4.4SPP modes of Ag NW by one end excitation
References
CHAPTER 5 PlasmonEnhanced Fluorescence Spectroscopy
5.1The Principle of PlasmonEnhanced Fluorescence
5.2PlasmonEnhanced Upconversion Luminescence
5.2.1Brief introduction
5.2.2Physical principle and mechanism
5.3Principle of PlasmonEnhanced FRET
References
CHAPTER 6 PlasmonEnhanced Raman Scattering Spectra
6.1SurfaceEnhanced Raman Scattering Spectroscopy
6.1.1Brief history of SERS spectroscopy
6.1.2Physical mechanism of SERS spectroscopy
6.2TipEnhanced Raman Scattering Spectroscopy
6.2.1Brief introduction of TERS spectroscopy
6.2.2Physical mechanism of TERS spectroscopy
6.2.3Setup of TERS
6.3RemoteExcitation SERS
References
CHAPTER 7 HighVacuum TipEnhanced Raman Scattering Spectroscopy
7.1Brief Introduction
7.1.1Brief description of setup of HVTERS
7.1.2Detailed description of setup of HVTERS
7.2The Application of HVTERS Spectroscopy in in situ PlasmonDriven Chemical Reactions
7.3Plasmonic Gradient Effect
7.4Plasmonic Nascissors
References
CHAPTER 8 Physical Mechanism of PlasmonExciton Coupling
Interaction
8.1Brief Introduction of Plexcitons
8.2PlasmonExciton Coupling Interaction
8.2.1Strong plasmonexciton coupling interaction
8.2.2Application of strong plasmonexciton coupling interaction
8.2.3Weak plasmonexciton coupling interaction
8.2.4Application of weak plasmonexciton coupling interaction
8.2.5Plexcitons
8.3Application
8.3.1Plasmonic electronsenhanced resonance Raman scattering and electronsenhanced fluorescence spectra
8.3.2Tipenhanced photoluminescence spectroscopy
8.3.3Femtosecond pumpprobe transient absorption spectroscopy
References
CHAPTER 9 PlasmonExcitonCoDriven Surface Catalysis Reactions
9.1PlasmonExcitonCoDriven Surface Oxidation Catalysis Reactions
9.2PlasmonExcitonCoDriven Surface Reduction Catalysis Reactions
9.3Unified Treatment for PlasmonExcitonCoDriven Oxidation and Reduction Reactions
References
CHAPTER 10 nlinear Optical Microscopies of CARS,TPEF,SHG,SFG and SRS
10.1Principles of nlinear Optical Microscopies
10.2Applications of nlinear Optical Microscopies
10.2.1Optical characterizations of 2D materials
10.2.2Highly efficient photocatalysis of gC3N4
10.2.3Optical characterizations of 3D materials
10.2.4Advances of biophotonics
10.2.5MSPRenhanced nlinear optical microscopy
References
Ackwledgements